Process for the production of durable titanium dioxide pigment

C - Chemistry – Metallurgy – 09 – C

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C09C 1/36 (2006.01)

Patent

CA 1113658

ABSTRACT OF THE DISCLOSURE Titanium dioxide pigments possessing outstanding durability are prepared by depositing in a slurry of TiO2, a dense silica coating upon the TiO2, followed by precipi- tating alumina in the slurry by a method comprising main- taining the TiO2 slurry at a temperature of 80 to 100°C during the silica deposition; rapidly adding sufficient sodium silicate to provide 1.5 to 15% silica, as a dense, amorphous, substantially continuous coating upon the TiO2; adjusting the pH of the slurry to a value of 9 to 10.5, and maintaining the pH at a temperature of 80 to 100°C for 15 to 60 mins.; and rapidly adding sufficient sodium aluminate and acid simultaneously to the slurry while maintaining the pH at 7 to 9, to deposit from about 1.5 to 5% alumina on the silica treated pigment.

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