Process for the production of high energy material

C - Chemistry – Metallurgy – 08 – F

Patent

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260/610, 260/463

C08F 8/30 (2006.01) C07C 201/02 (2006.01) C07C 203/04 (2006.01) C08C 19/40 (2006.01)

Patent

CA 1267419

ABSTRACT A process for the production of a high energy material involves reacting, in an inert organic solvent, a heterocyclic compound selected from oxirane, aziridine, oxetane or azetidine with a nitrogen oxide selected from dinitrogen tetroxide (N2O4) and dinitrogen pentoxide (N2O5) and, when the nitrogen oxide is N2O4, oxidising the O - or N - nitroso sub- stituent or substituents in the product obtained to O - or N - nitro substituent or substituents. The heterocyclic compounds may be substituted or unsubstituted. In the former case the preferred substituents groups are halogen, alkyl, alkenyl, nitro and epoxy (as is epoxidised polybutadiene). The solvent is preferably a chlorinated alkane. Novel nitrated derivatives of polybutadiene, in which between 1% and 25% of the carbon atoms in the polymer are sub- stituted by nitrate (ONO2), are also provided. These novel materials are liquid rubbers when the polybutadiene starting material has a molecular wight between 2000 and 10000.

431284

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