Process for the production of hydrocarbons from...

C - Chemistry – Metallurgy – 07 – C

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260/705

C07C 1/26 (2006.01) C07C 9/00 (2006.01) C07C 11/02 (2006.01)

Patent

CA 1232616

ABSTRACT OF THE DISCLOSURE Process for the production of hydrocarbons from hetero-substituted alkanes A product comprising hydrocarbons having at least 2 carbon atoms is produced by contacting a monohalomethane at elevated temperature, e.g. 200 to 600°C, with a synthetic crystalline aluminosilicate zeolite having a silica to alumina molar ratio of at least 12:1 and containing cations of either hydrogen, copper or a metal capable of forming an amphoteric oxide, which cations are introduced either by exchange and/or by deposition, provided that when the cation is hydrogen the zeolite is Theta-l. At temperatures below 330°C the product predominantly comprises aliphatic hydrocarbons, of which a substantial proportion is isoalkanes and isoalkenes.

470117

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