Process for the production of hydrocarbyl formates

Details Process for the production of hydrocarbyl formates Process for the production of hydrocarbyl formates

C - Chemistry, Metallurgy

07

C

260/495, 260/529

C07C 53/04 (2006.01) B01J 23/46 (2006.01) B01J 23/56 (2006.01) C07C 29/153 (2006.01) C07C 51/09 (2006.01) C07C 69/06 (2006.01)

Patent

CA 1208235

ABSTRACT OF THE DISCLOSURE Hydrocarbyl formates, convertible by hydrolysis into formic acid, are produced by reacting carbon dioxide and hydrogen with a compound of formula ROH wherein R is a hydrocarbyl group in the presence of a substantially insoluble compound of an element selected from Groups III to VIII of the Periodic Table, which element exhibits amphoteric or basic properties, and as catalyst a compound of a transition metal of Group VIa, VIIa or VIII of the Periodic Table, particularly rhodium, ruthenium or iridium.

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