C - Chemistry – Metallurgy – 08 – F
Patent
C - Chemistry, Metallurgy
08
F
402/301
C08F 222/06 (2006.01) C08F 210/14 (2006.01) D21H 17/43 (2006.01)
Patent
CA 1109999
A PROCESS FOR THE PRODUCTION OF PAPER SIZING AGENTS Abstract of the Disclosure An improved process for the production of a substantially equimolecular copolymer of maleic acid anhydride and diiso- butylene in which from 10 to 100 mole % of the anhydride groups are esterified with linear or branched aliphatic monoalcohols containing from 1 to 20 carbon atoms or with cycloaliphatic monoalcohols containing from 5 to 6 carbon atoms to form the corresponding semiesters, wherein shortly before or after the end of the solution or suspension copolymerisation of maleic acid anyhdride and diisobutylene a monomer corresponding to the general formula Image in which R = H, CH3, C2H5, -OR2, -O-CO-CH3, Image Image Image R1 = H , CH3 and R2 = a linear or branched alkyl group containing from 1 to 4 carbon atoms, or mixtures of these monomers with one another are added to the polymerisation mixture in quantities of from 1 to 12 mole %, based on the maleic acid anhydride used. The aqueous or aqueous- alcoholic alkali, amine or ammonium salt solutions of the semiesters of the copolymer are highly effective as anionic sizing agents for paper.
295041
Fischer Heinz
Kolb Gunter
Muller Friedhelm
Sackmann Gunter
Aktiengesellschaft Bayer
Fetherstonhaugh & Co.
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