Process for the production of phenols

C - Chemistry – Metallurgy – 07 – C

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C07C 37/56 (2006.01) B01J 23/889 (2006.01) C07C 39/02 (2006.01) C07C 41/01 (2006.01) C07C 41/26 (2006.01) C07C 51/367 (2006.01)

Patent

CA 1170275

M-12-29149C/Ho/82 ABSTRACT OF THE DISCLOSURE A process for producing phenols from benzene- monocarboxylic acids, or their salts, esters, or anhydrides is described, comprising contacting these starting materials with molecular oxygen-containing gas and steam in a liquid phase in the presence of a copper compound, a manganese compound, and a rare earth element compound. This process can be performed either by a one-step reaction method or by a two-step reaction method. In accordance with the present process, the formation of by-products such as high boiling by-products or diphenyl ethers is inhibited and the selectivity of phenols can be greatly increased.

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