Process for the production of propionate esters

C - Chemistry – Metallurgy – 07 – C

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260/495, 202/58

C07C 67/38 (2006.01) C07C 69/24 (2006.01)

Patent

CA 1318328

T 245 A B S T R A C T PROCESS FOR THE PRODUCTION OF PROPIONATE ESTERS Integrated process for the simultaneous production of methyl propionate (MEP) and a second propionate ester by catalytically carbonylating C2H4 with CO and CH3OH, isolating MEP from the carbonylation reaction mixture, catalytically transesterifying MEP with a second alcohol to form the second propionate ester, isolating a CH3OH-MEP azeotrope from the transesterification reaction mixture, and recirculating the isolated azeotrope to the carbonylation. T13/T245

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