Process for the production of synthesis gas by the catalysed...

C - Chemistry – Metallurgy – 01 – B

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C01B 3/00 (2006.01) C01B 3/22 (2006.01) C01B 3/40 (2006.01)

Patent

CA 1084709

ABSTRACT Synthesis gas is produced by contacting methanol in the vapour phase with a catalyst which is a supported metal of Group VIII of the Periodic Table either alone or in combination with one or more others metals from Groups I to VIII, excluding binary combinations of copper and nickel, typically at a temperature in the range 200 to 600°C and at a pressure in the range 0 to 50 atmospheres. The best results are achieved with a mixture of rhodium and copper supported on silica, a 100% molar yield of carbon monoxide on methanol fed obtained at 450°C, atmospheric pressure and 3.5 second contact time.

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