Process for the production of tertiary alkyl ethers and...

C - Chemistry – Metallurgy – 07 – C

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260/648, 260/706

C07C 41/06 (2006.01) C07C 2/10 (2006.01) C07C 11/02 (2006.01) C07C 29/04 (2006.01) C07C 31/02 (2006.01) C07C 43/04 (2006.01)

Patent

CA 2028135

2028135 9011268 PCTABS00002 A process for producing lower alkyl tertiary alkyl ethers or tertiary alkyl alcohol, such as methyl tertiary butyl ether (MTBE), methyl tertiary amyl ether (TAME) or tertiary butyl alcohol, wherein the 1-alkene component of the hydrocarbon feedstream to an etherification or olefin hydration process is separated by selective oligomerization in contact with a reduced chromium on silica support catalyst producing useful hydrocarbons of higher molecular weight, such as gasoline, distillate and lube range hydrocarbons. It has further been found that separation of the 1-alkene component of the hydrocarbon feedstream can be accomplished in an oligomerization process integrated either upstream or downstream of the etherification step.

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