C - Chemistry – Metallurgy – 07 – C
Patent
C - Chemistry, Metallurgy
07
C
260/472, 260/491
C07C 69/16 (2006.01) B01J 23/44 (2006.01) B01J 23/62 (2006.01) B01J 27/00 (2006.01) B01J 31/04 (2006.01) C07C 67/05 (2006.01) C07C 67/055 (2006.01) C07C 69/007 (2006.01) C07C 69/12 (2006.01)
Patent
CA 1131246
(Jap. 142,244/78) ABSTRACT OF THE DISCLOSURE The invention relates to a process for the production of an unsaturated glycol diester by the reaction of a conjugated diene compound, a carboxylic acid and molecular oxygen in the presence of a solid catalyst. For example, 1,4-diacetoxy-2-butene is prepared at high conversion and high selectivity by reacting butadiene, molecular oxygen and acetic acid in the presence of a solid catalyst containing palladium, tellurium and at least one element selected from the group consisting of tin, germanium and zinc. The production is an intermediate for the preparation of 1,4-butanediol.
339716
Kamiyama Setsuo
Kaneko Katsumi
Okumura Yoshiharu
Shiozawa Kouji
Borden Ladner Gervais Llp
Toa Nenryo Kogyo K.k.
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