Process for the recycling of solid phase bonded ctc-resin

C - Chemistry – Metallurgy – 08 – F

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C08F 8/20 (2006.01) C08F 12/32 (2006.01)

Patent

CA 2506533

The present invention relates to a recycling process for the preparation of solid phase bonded 2-chlorotrityl chloride (2-CTC resin) useful for solid phase peptide synthesis. Specifically what is claimed is a process for the preparation of solid phase bonded 2-chlorotrityl chloride (2-CTC resin) of formula I, wherein Ps is a polymeric support and n has the following meaning: 1 >= n> 0 comprising the reaction of solid phase bonded 2-chlorotrityl of formula II, wherein R is OH or/and OC1-4-alkyl or/and NR'R" wherein R' and R" independently of each other represent C1-4-alkyl, or R' and R" together with the nitrogen to which they are bonded represent a 5 to 8 membered heterocyclic radical in the presence of a chlorinating agent and an organic solvent.

L'invention concerne un procédé de recyclage destiné à la préparation d'un 2-chlorotrityl chlorure (2-CTC résine) lié en phase solide et utile pour une synthèse de peptides en phase solide. Plus précisément, l'invention concerne un procédé de préparation d'un 2-chlorotrityl chlorure lié en phase solide (2-CTC résine) de formule I, dans laquelle Ps représente un support polymère et n a la signification suivante: 1 = n> 0, comprenant la réaction du 2-chlorotrityl lié en phase solide de formule II, dans laquelle R désigne OH et/ou un OC¿1-4?-alkyle et/ou NR'R", où R' et R" représentent de manière indépendante un alkyle en C¿1-4?,¿ ?ou R' et R" conjointement avec l'azote auquel ils sont liés représentent un radical hétérocyclique comprenant entre 5 et 8 chaînons en présence d'un agent de chloration et d'un solvant organique.

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