Process for the selective production of acetic acid

B - Operations – Transporting – 01 – J

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B01J 23/16 (2006.01) B01J 23/64 (2006.01) B01J 23/656 (2006.01) C07C 51/215 (2006.01) C07C 51/25 (2006.01) C07C 53/08 (2006.01)

Patent

CA 2255973

A process for the selective production of acetic acid from a gaseous supply of ethane, ethylene or mixtures thereof and oxygen at high temperature, in which the gaseous supply is brought into contact with a catalyst containing the elements Mo, Pd, Re, X and Y in the atom-gram ratios a:b:c:d:e in combination with oxygen, of formula (I) Mo e Pd b Re c X d Y e, where X is Cr, Mn, B, Ta, Ti, V and/or W; Y is Bi, Ce, Co, Cu, Te Fe, Li, K, Na, Rb, Be, Mg, Ca, Sr, Ba, Ni, P, Pb, Sb, Si, Sn, Tl and/or U; the indices a, b, c, d and e stand for the atom-gram ratios of the corresponding elements, where a = 1, b > 0, c > 0, d = 0.05 to 2 and e = 0 to 3.

L'invention concerne un procédé de production sélective d'acide acétique par alimentation gazeuse d'éthane, d'éthylène ou leurs mélanges, ainsi que d'oxygène à haute température. Ledit procédé est caractérisé en ce que l'alimentation gazeuse est mise en contact avec un catalyseur qui contient les éléments Mo, Pd, Re, X et Y dans des rapports atome gramme a:b:c:d:e en combinaison avec l'oxygène, de formule (I) MoaPdbRecXdYe, dans laquelle X représente Cr, Mn, Nb, B, Ta, Ti, V et/ou W; Y représente Bi, Ce, Co, Cu, Te, Fe, Li, K, Na, Rb, Be, Mg, Ca, Sr, Ba, Ni, P, Pb, Sb, Si, Sn, Ti et/ou U; les indices a, b, c, d et e représentent les rapports atome gramme des éléments correspondants, à savoir a = 1, b > 0, c > 0, d = 0,05 à 2, e = 0 à 3.

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