Process for the simultaneous coproduction and purification...

C - Chemistry – Metallurgy – 07 – C

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C07C 67/08 (2006.01) C07C 67/54 (2006.01) C07C 69/14 (2006.01)

Patent

CA 2431365

This invention relates to a process for the simultaneous coproduction of ethyl acetate and isopropyl acetate. The esterification reaction comprises contacting acetic acid with a mixed alcohol stream of ethanol and isopropanol. Exemplified is a purified, Fischer Tropsch derived mixture of ethanol and isopropanol. The esterification reaction occurs in the presence of an acidic catalyst in a liquid phase reaction system. The resultant crude reaction step product is separated and purified by distillation to produce acetate ester products having greater than 99.5 wt% purity.

La présente invention concerne un procédé de coproduction simultanée d'acétate d'éthyle et d'acétate d'isopropyle. La réaction d'estérification consiste à mettre de l'acide acétique en contact avec un mélange d'alcool à base d'éthanol et d'isopropanol. Un mode de réalisation de la présente invention concerne un mélange dérivé et purifié Fischer-Tropsch d'éthanol et d'isopropanol. La réaction d'estérification se produit en présence d'un catalyseur acide dans un système de réaction à phase liquide. Le produit brut issu de cette étape réactionnelle est séparé et purifié par distillation pour produire des produits à base d'acétate ester ayant une pureté supérieure à 99,5 % en masse.

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