Process for the transfer of alkyl groups in dialkyl...

C - Chemistry – Metallurgy – 07 – C

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C07C 321/14 (2006.01) C07C 319/22 (2006.01) C07C 319/24 (2006.01)

Patent

CA 2102580

PROCESS FOR THE TRANSFER OF ALKYL GROUPS IN DIALKYL TRISULFIDES AND MERCAPTANS Abstract of the Disclosure The alkyl groups of dialkyl trisulfides are exchanged with the alkyl groups of mercaptans by reacting a tertiary dialkyl trisulfide with an alkyl mercaptan having a greater number of carbon atoms in its alkyl group than said trisulfide in the presence of an acidic or basic type catalyst for a time and a temperature sufficient to produce a dialkyl trisulfide having at least one transferred alkyl group from said mercaptan. -13-

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