Process for their resolution of racemates of optically...

C - Chemistry – Metallurgy – 07 – D

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530/5.06

C07D 209/52 (2006.01) C07D 209/42 (2006.01) C07D 209/54 (2006.01) C07K 5/02 (2006.01) C07K 5/06 (2006.01)

Patent

CA 1317067

ABSTRACT The invention relates to a process for the preparation of optically pure compounds of the general formula IIa or IIb Image (IIa) Image (IIb) in which A, B1, B2, C, R1, R2, X, Y and Z have the indicated meanings, which comprises reacting, in the presence of a condensing agent or, where appropriate, as an active ester, optically pure compounds of the formula Ia or Ib Image Image (Ia) (Ib) in which A, B1, B2, C and R have the indicated meanings with optically pure compounds of the formula III (III) Image in which R, R1, R2, X, Y and Z have the indicated meanings, splitting off the radical R by hydrogenolysis or hydrolysis, and, where appropriate, converting the optically pure compounds of the formula Ia or Ib into physiologically tolerated salts.

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