Process for trapping gaseous ruthenium on polyvinyl...

C - Chemistry – Metallurgy – 22 – B

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C22B 11/00 (2006.01) C22B 11/02 (2006.01) C22B 61/00 (2006.01) G21C 19/48 (2006.01)

Patent

CA 2090810

DESCRIPTIVE ABSTRACT The invention relates to a process for trapping gaseous ruthenium on polyvinyl pyridine, more particularly usable for recovering radioactive ruthenium from irradiated nuclear fuels. This process consists of contacting a gas containing ruthenium in gaseous form with an adsorbent (11b) constituted by a vinyl pyridine polymer or copolymer for fixing the ruthenium to the latter. The gas can be constituted by vapours from a concentrate of fission products containing ruthenium, which has been heated (at 31) in the presence of an oxidizing agent for volatilizing the ruthenium. (Fig. 1) B. 10821 MDT

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