Process for upgrading light olefins in a turbulent fluidized...

C - Chemistry – Metallurgy – 07 – C

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260/688, 260/706

C07C 2/12 (2006.01) B01J 29/40 (2006.01) C07C 2/00 (2006.01) C07C 9/14 (2006.01) C07C 11/02 (2006.01) C10G 50/00 (2006.01)

Patent

CA 1279659

PROCESS FOR UPGRADING LIGHT OLEFINS IN A TURBULENT FLUIDIZED CATALYST BED REACTOR ABSTRACT A fluidized bed catalytic process for conversion of light olefinic gas feedstock containing ethene to produce hydrocarbons rich in C5+ liquids, comprising the steps of maintaining a fluidized bed of zeolite catalyst particles in a turbulent reactor bed at a temperature of about 315 to 510°C, said catalyst having an apparent particle density of about 0.9 to 1.6 g/cm3 and a size range of about 1 to 150 microns, and average catalyst particle size of about 20 to 100 microns containing about 10 to 25 weight percent of fine particles having a particle size less than 32 microns; passing hot feedstock vapor upwardly through the fluidized catalyst bed under turbulent flow conditions; maintaining turbulent fluidized bed conditions through the reactor bed between transition velocity and transport velocity at a superficial fluid velocity of about 0.3 to 2 meters per second; and recovering hydrocarbon product containing a major amount of C5+ hydrocarbons and containing C3-C5 alkanes and alkenes in the ratio of about 0.2:1 to 5:1.

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