Process for washing gas formed by gasifying black liquor

D - Textiles – Paper – 21 – C

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D21C 11/12 (2006.01) D21C 11/00 (2006.01) D21C 11/06 (2006.01)

Patent

CA 2193516

Process for recovering chemicals and energy from black liquor, where the black liquor is gasified with CO, CO2. CH4, H2, and H2S, in gaseous form, and Na2CO3, NaOH and Na2S, in the form of drops of smelt, being principally formed. The mixture of gas and smelt is cooled, in a first stage, by direct contact with a cooling liquid, whereupon a part of the cooling liquid is volatilized, and the smelt drops are separated off and dissolved in the remaining part of the cooling liquid with the formation of a liquid bath (6) of green liquor. In a second stage, the gas is washed and saturated with moisture by direct contact with a washing liquid bath (13). After the gas has been washed in the second stage, energy in the form of thermal energy and condensation heat is recovered from the gas in an indirect condenser (16). The contact between the gas and the liquid bath (6), consisting of green liquor, in the first stage is substantially less than the contact between the gas and the washing liquid bath (13), in the second stage. This is achieved, by the gas in the first stage not being permitted to bubble through the liquid bath (6), consisting of green liquor, in contrast to the second stage, in which the gas is caused to buble through the washing liquid bath (13).

Procédé de récupération de produits chimiques et d'énergie contenus dans de la liqueur noire consistant à la gazéifier en CO, CO2, CH4, H2, et H2S, sous forme gazeuse et en Na2CO3, NaOH et Na2S sous forme de gouttelettes fondues. Le mélange de gaz et de gouttelettes est ensuite refroidi dans une première étape par contact direct avec un liquide de refroidissement lequel est ensuite partiellement volatilisé tandis que les gouttelettes sont séparées et dissoutes dans le reliquat du liquide de refroidissement de façon à former un bain liquide (6) de liqueur verte. Dans une seconde étape, le gaz est lavé puis saturé en humidité par contact direct avec le bain liquide de lavage (13). Après quoi l'énergie thermique et la chaleur de condensation du gaz sont récupérées dans un condenseur indirect (16). Le contact entre le gaz et le bain liquide (6) de liqueur verte de la première étape est sensiblement moindre que celui entre le gaz et le bain liquide (13) de lavage de la deuxième étape car dans la première étape, le gaz ne peut pas bouillonner dans le bain liquide (6) de liqueur verte, tandis qu'il le peut dans le bain liquide (13) de lavage pendant la deuxième étape.

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