Process for working up distillation residues from the...

C - Chemistry – Metallurgy – 07 – C

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260/495.3

C07C 69/24 (2006.01) C07C 45/50 (2006.01)

Patent

CA 1105488

ABSTRACT OF THE DISCLOSURE Distillation residues from the hydroformylation of propene are worked up by adding from 1 to 2 moles, based on the acid content, of n- butanol and/or isobutanol, and carrying out esterification in the presence of a catalytic amount of a sulphonic acid and at a temperature of 50 to 200 C, water formed during the reaction being separated off. The ester- ification product is further processed in known manner, for example by dis- tillation and hydrogenation to give a product consisting predominantly of n-butanol, isobutanol and 2-ethylhexanol.

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