Process of forming a negative pattern in a photoresist layer

H - Electricity – 05 – K

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H05K 3/06 (2006.01) G03F 7/022 (2006.01) G03F 7/26 (2006.01)

Patent

CA 1275846

ABSTRACT OF THE DISCLOSURE: A process of forming high resolution negative patterns in a photoresist layer, comprises the steps of (a) coating a substrate with a layer of a photosensitive resin comprising a polymer, preferably a phenolic polymer, mixed or bound to a photoactive compound such as a diazoquinone, (b) exposing the layer to ultraviolet or visible light through a mask, (c) treating the layer with a silicon compound (e.g. hexamethyldisilazane) and (d) dry developing by plasma etching (e.g. an oxygen plasma) to remove the non- irradiated portions of the layer. The silicon compound is able to diffuse selectively into the irradiated portions of the layer and fix in these portion. By dry etching, a silicon oxide etch mask is formed which protects these irradiated portions efficiently throughout the process. The process is useful in the manufacture of semiconductor devices, including integrated circuits.

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