B - Operations – Transporting – 01 – J
Patent
B - Operations, Transporting
01
J
252/93.A, 260/70
B01J 21/00 (2006.01) B01J 21/14 (2006.01) B01J 23/22 (2006.01) B01J 23/28 (2006.01) B01J 37/00 (2006.01) C03C 14/00 (2006.01) C07C 5/333 (2006.01) C07C 5/42 (2006.01) C07C 11/167 (2006.01)
Patent
CA 2021573
A process far the production of olefins and diolefins, such as 1,3-butadiene, comprising contacting an aliphatic hydrocarbon, such as butane, with a heterogeneous catalyst composition containing reactive oxygen under reaction conditions such that a more highly unsaturated aliphatic hydrocarbon is selectively formed in a high productivity. The catalyst is a composition comprising a catalyst component of magnesia, an oxide of molybdenum, a Group IA metal oxide promoter, and optionally vanadium oxide. In a preferred embodiment, the catalyst composition also comprises a support component of magnesium and alumina and/or magnesium aluminate spinel. The present catalyst has high surface area and high attrition resistance.
Khazai Bijan
Murchison Craig B.
Vrieland G. Edwin
Smart & Biggar
The Dow Chemical Company
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