Process of producing a fuel gas by the catalytic reaction of...

C - Chemistry – Metallurgy – 01 – B

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C01B 3/00 (2006.01) B01J 23/755 (2006.01) B01J 23/78 (2006.01) C01B 3/22 (2006.01) C01B 3/32 (2006.01) C01B 3/40 (2006.01) C10L 3/08 (2006.01)

Patent

CA 1077718

ABSTRACT OF THE DISCLOSURE : The production of a methane-containing fuel gas is carried out by supplying water vapor and vaporized methanol under superatmospheric pressure on a nickel catalyst, the water vapor and vaporized methanol being supplied at a weight ratio of about 0.5 to 1.5 and at inlet temperature of about 300 to 500°C to a reactor and being reacted therein under adiabatic conditions and under a pressure in the range of about 10 to 40 bars; the nickel catalyst contains 25-50% by weight nickel in the form of the compound Ni5MgAl2O9, 5-40% by weight high- alumina cement, and at least 5% by weight zirconium dioxide. The product gas leaving the reactor at temperatures of about 500 to 700°C is subsequently cooled. The process of the invention has the advantage of producing a gas having a high calorific value without the supply of air so that the carbon monoxide content of the product gas is minimized.

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