Process to produce silyl ketene acetals

C - Chemistry – Metallurgy – 07 – F

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260/447.6

C07F 7/18 (2006.01) C07F 7/12 (2006.01)

Patent

CA 1332245

A PROCESS TO PRODUCE SILYL KETRNE ACETALS ABSTRACT A process for the preparation of silyl ketene acetals of the formula, R2C=C(OSiRnX3-n)(OZ) or Image . The process comprises contacting an alpha-ester of a carboxylic acid with an alkali metal in the presence of an excess of an organohalosilane, wherein the alpha-ester has the formula, Image or Image ; and the organohalosilane has the formula RnSiX4-n; and facilitating reaction among the alpha-ester, the alkali metal and the organochlorosilane to form the silyl ketene acetal and an alkali metal halide or an alkali metal alkoxide.

581312

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