Prodrugs of hiv replication inhibiting pyrimidines

C - Chemistry – Metallurgy – 07 – D

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C07D 239/46 (2006.01) A61K 31/505 (2006.01) A61P 31/18 (2006.01) C07D 239/48 (2006.01) C07D 401/12 (2006.01)

Patent

CA 2407754

The present invention concerns compounds of the formula (I): (A1)(A2)N-R1, the N-oxide forms, the pharmaceutically acceptable addition salts, the quaternary amines and stereochemically isomeric forms thereof, wherein R1 is substituted C1-6alkyl; -S(=O)-R8; -S(=O)2-R8; C7-12alkylcarbonyl; optionally substituted C1-6alkyloxycarbonylC1- 6alkylcarbonyl; with R8 being C1-6alkyl, aryl1 or Het1; (A1)(A2)N- is the covalently bonded form of the corresponding intermediate of the formula (A1)(A2)N-H, which is a HIV replication inhibiting pyrimidine of formula (II).

La présente invention concerne des composés de formule (I): (A1)(A2)N-R<1>, leurs formes N-oxyde, leurs sels d'addition, acceptables d'un point de vue pharmaceutique, leurs amines quaternaires, ainsi que leurs formes stéréoisomères. Dans cette formule, R<1> représente alkyle C1-6 substitué; -S(=O)-R<8>; -S(=O)2-R<8>; alkylcarbonyle C7-12; alkylcarbonyle C1-6 d'alkyloxycarbonyle C1-6 éventuellement substitué; R<8> étant alkyle C1-6, aryle<1> ou Het<1>; (A1)(A2)N- représente la forme à liaison covalente du produit intermédiaire correspondant, de formule (a): (A1)(A2)N-H, qui est une pyrimidine inhibant la réplication du VIH, de formule (II).

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