C - Chemistry – Metallurgy – 07 – C
Patent
C - Chemistry, Metallurgy
07
C
260/491.8
C07C 69/16 (2006.01) C07C 67/293 (2006.01) C07C 67/37 (2006.01)
Patent
CA 1133931
PRODUCTION OF 1,1-DIACETOXIETHANE ABSTRACT OF THE DISCLOSURE: The invention relates to an improved process for making 1,1-diacetoxiethane by reacting methyl acetate and/or dimethylether with carbon monoxide and hydrogen under practically anhydrous conditions, at temperatures of 350 to 575 K, under pressures of 1 to 300 bars, and in the presence of a catalyst system containing noble metals belonging to group VIII of the periodic system of the elements, or compounds thereof, and iodine and/ or its compounds. The improved process is effected in the presence of a catalyst system containing, as ad- ditional ingredients, an aliphatic carboxylic acid having 1 to 8 carbon atoms, a heterocyclic aromatic compound, in which at least one hetero atom is a quaternary nitrogen atom, and a manganese or rhenium compound.
361681
Erpenbach Heinz
Gehrmann Klaus
Kohl Georg
Kubbeler Hans-Klaus
Fetherstonhaugh & Co.
Hoechst Aktiengesellschaft
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