Production of 2-bromo-alpha-ergocryptine and its acid...

C - Chemistry – Metallurgy – 07 – D

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260/206.3

C07D 519/02 (2006.01) C07D 457/12 (2006.01)

Patent

CA 1294956

ABSTRACT OF THE DISCLOSURE: 2-Bromo-alpha-ergocryptine, the potent inhibitor of prolactin /luteotropic hormone/, is prepared in high yield and purity grade by the bromination of alpha-ergocryp- tine with elemental bromine in chlorinated aliphatic hydrocarbons and/or tetrahydrofuran in the presence of catalytic amounts of Lewis acids, preferably boron tri- fluoride, in the temperature range of from -40 to 0°C and optionally converted as known per se into its acid addition salt, preferably methanesulfonate.

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