Production of carboxylic acids and esters

C - Chemistry – Metallurgy – 07 – C

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260/539.6

C07C 53/42 (2006.01) C07C 51/12 (2006.01) C07C 51/14 (2006.01) C07C 51/58 (2006.01)

Patent

CA 1173057

ABSTRACT OF THE DISCLOSURE An acylium anion product, e.g., isobutyryl fluoride, is formed by reacting carbon monoxide, an organic compound, propylene, and anhydrous hydrogen fluoride, in a liquid mixture while feeding the carbon monoxide and organic compound, e.g., propylene, into the liquid mixture's vapor phase which is maintained above the supercritical tempera- ture of the vapor mixture at substantially the same rate as the carbon monoxide, organic compound propylene, and anhy- drous acid (hydrogen fluoride) react, under the conditions described herein.

404487

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