Production of glycolaldehyde by hydrous thermolysis of sugars

C - Chemistry – Metallurgy – 07 – C

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Details

C07C 47/19 (2006.01) C07C 45/00 (2006.01) C07C 45/60 (2006.01) C07C 45/67 (2006.01) C07C 45/78 (2006.01) C07C 45/79 (2006.01)

Patent

CA 2326471

The present invention provides a method for the production of glycolaldehyde with high specificity. The hydrous thermolysis consists of the spraying of aqueous sugar solutions containing from 25 to 80% of water but preferably 30 to 60% water, as a fine mist into a reactor held at the between 500 and 600°C, but preferably between 520 and 560°C and the condensation of the resulting vapourous product in a surface condenser with optional heat recovery. The residence time of the vaporous product in the reactor should be in the range 0.1 -5 seconds, but preferably in the range 0.5 to 2 seconds. Aldose monomeric sugars, preferably glucose (also known as dextrose), are preferred for use in the aqueous solution. The yield of glycolaldehyde in the condensed liquid is minimum 50% by weight of the sugar fed for glucose solutions.

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