Production of hydrofluoroalkanes

C - Chemistry – Metallurgy – 07 – C

Patent

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Details

C07C 19/08 (2006.01) C07C 17/08 (2006.01) C07C 17/20 (2006.01) C07C 17/21 (2006.01) C07C 17/358 (2006.01)

Patent

CA 2137234

A process for the co-production of two or more hydrofluoroalkanes which comprises contacting an alkene or a halogenated alkane with hydrogen fluoride at elevated temperature in the presence of a fluorination catalyst to produce a first hydrofluoroalkane and wherein an organic precursor to a second hydrofluoroalkane is provided in the process whereby to produce a second hydrofluoroalkane in addition to the first hydrofluoroalkane. In particularly preferred embodiments of the process, the first hydrofluoroalkane is 1,1,1,2-tetrafluoroethane derived from 1-chloro-2,2,2- trifluoroethane or trichloroethylene and the second hydrofluoroalkane is one or more of pentafluoroethane, difluoromethane and 1,1,2,2-tetrafluoroethane.

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