Production of hydrogen and carbon monoxide

C - Chemistry – Metallurgy – 01 – B

Patent

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Details

C01B 3/42 (2006.01) B01D 53/02 (2006.01) B01D 53/12 (2006.01) B01J 8/00 (2006.01) B01J 8/02 (2006.01) B01J 8/08 (2006.01) B01J 8/18 (2006.01) C01B 3/04 (2006.01) C01B 3/36 (2006.01) C01B 3/38 (2006.01) C01B 3/44 (2006.01) C01B 13/02 (2006.01) C01B 17/04 (2006.01) C01B 21/02 (2006.01) C01B 31/18 (2006.01)

Patent

CA 2302989

Partial oxidation of hydrocarbons to produce hydrogen and carbon monoxide is carried out by a fixed bed or a fluidized bed process which includes the steps of passing steam and/or carbon dioxide through a perovskite-type ceramic mixed conductor in an adsorption zone at an elevated temperature, thereby at least partially saturating the mixed conductor with oxygen and producing hydrogen and/or carbon monoxide, and subsequently contacting the hot, at least partially oxygen-saturated mixed conductor with a hydrocarbon in a partial oxidation reaction zone. During the partial oxidation reaction phase of the process, the sorbed oxygen reacts with the hydrocarbon, thereby producing hydrogen and carbon monoxide.

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