Production of isocyanates

C - Chemistry – Metallurgy – 07 – D

Patent

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402/123, 260/303

C07D 273/00 (2006.01) C08G 18/00 (2006.01) C08G 71/04 (2006.01)

Patent

CA 1097655

354215 ABSTRACT OF THE DISCLOSURE Process for the preparation of organic isocyanates in which a furoxan is heated in the presence of a vicinal di- keto compound containing two adjacent keto carbonyl groups. When the furoxan ring is fused to an organic ring system di-isocyanates are produced. An adduct of the furoxan and the diketo compound may be isolated from the reaction mixture and used as a stable isocyanate precursor in, for example, a "one- pot" polyurethane composition. The adduct may be represented by the structure Image wherein X represents an acyclic or cyclic divalent hydrocarbyl group and Y, Z which may be the same or different are hydro- carbyl groups which are either separate or combined into one cyclic system.

354215

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