Production of methyl and ethylamines with rhodium- iron...

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260/609

B01J 23/89 (2006.01)

Patent

CA 1133520

12,641 PRODUCTION OF METHYL AND ETHYLAMINES WITH RHODIUM-IRON CATALYSTS ABSTRACT OF THE DISCLOSURE A heterogeneous process for electively producing monoamines in which the nitrogen is bonded only to methyl, ethyl, hydrogen or combinations thereof which comprises contacting a mixture of carbon monoxide, hydrogen and a nitrogen-containing compound selected from the group con- sisting of ammonia, nitric oxide and mixtures thereof with a heterogeneous solid catalyst comprising rhodium and iron. The monoamines of the invention are formed in a collective amount of at least 50 weight percent of the total amine products of the reaction. SPECIFICATION 1.

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