Production of non-conjugated diolefins

C - Chemistry – Metallurgy – 07 – C

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260/702.1

C07C 6/04 (2006.01) C07C 11/12 (2006.01)

Patent

CA 1327213

ABSTRACT OF THE DISCLOSURE THE PRODUCTION OF NON CONJUGATED DIOLEFINS Non-conjugated diolefins having two formula: Image (I) wherein R3 and R4 are either hydrogen, alkyl or substituted alkyl and n is an interger, are produced by the process comprising reacting a diolefin having the formula: Image (II) wherein R3 and R4 and n are the same as in formula (I) and R1 and R2 are either hydrogen, alkyl or substituted alkyl, with ethylene in the presence of a disproportionation catalyst comprising supported rhenium heptoxide and a promoter comprising either a tetraalkyl tin compound or a trialkyl aluminium compound.

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