Production of polyolefins containing long chain branches by...

C - Chemistry – Metallurgy – 08 – F

Patent

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C08F 10/02 (2006.01) B01J 8/10 (2006.01) C08F 4/626 (2006.01) C08F 4/642 (2006.01) C08F 10/00 (2006.01) C08F 210/16 (2006.01) C08F 4/659 (2006.01) C08F 4/6592 (2006.01)

Patent

CA 2138572

A gas phase process for producing polyethylene containing long chain branches is disclosed and claimed. The polymerization process involves contacting ethylene under polymerization conditions in the gas phase and at a temperature above 65°C, with a catalyst composition which includes a) at least one bridged metallocene having at least two cyclic pi-bonded moieties in association with a metal atom, the cyclic pi-bonded moieties being joined together via a bridging linkage one or two atoms long, and b) an activating cocatalyst; the catalyst composition being effective to result in incorporation of an average of up to 3 long chain branches per 1000 carbon atoms in the main polyethylene chain.

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Profile ID: LFCA-PAI-O-1972013

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