Production of terephthalic acid

C - Chemistry – Metallurgy – 07 – C

Patent

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260/510.8

C07C 63/26 (2006.01) C07C 51/265 (2006.01)

Patent

CA 1180026

ABSTRACT OF THE DISCLOSURE Disclosed is a process for the continuous production of terephthalic acid from p-xylene, com- prising the steps of oxidizing p-xylene in a first oxidation zone in the presence of not more than about 10 weight % of water and a cobalt/manganese catalyst up to a conversion of about 15% terephthalic acid; oxidizing the partially-oxidized compounds in a second oxidation zone in the presence of an addi- tional amount of water up to about 20 to 70% by weight and in the presence of an additional amount of the catalyst up to a conversion of about 50% by weight terephthalic acid; stripping p-xylene va- pors from the second oxidation zone; separating crystals of crude terephthalic acid from the effluent from the second oxidation zone from the soluble components of the effluent; countercurrent- ly washing the separated crystals with fresh water to produce a slurry; recycling a part of soluble components to the second oxidation zone, and an- other part of the first oxidation zone to provide the latter with heavy metal catalyst; and recovering purified terephthalic acid by recrystallizing the crystals contained in the slurry.

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