Protected active metal electrode and battery cell structures...

H - Electricity – 01 – M

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H01M 12/04 (2006.01) H01M 4/12 (2006.01) H01M 6/34 (2006.01) H01M 12/06 (2006.01)

Patent

CA 2555637

Active metal and active metal intercalation electrode structures and battery cells having ionically conductive protective architecture including an active metal (e.g., lithium) conductive impervious layer separated from the electrode (anode) by a porous separator impregnated with a non-aqueous electrolyte (anolyte). This protective architecture prevents the active metal from deleterious reaction with the environment on the other (cathode) side of the impervious layer, which may include aqueous or non-aqueous liquid electrolytes (catholytes) and/or a variety electrochemically active materials, including liquid, solid and gaseous oxidizers. Safety additives and designs that facilitate manufacture are also provided.

Cette invention concerne des structures d'électrode et des éléments de batterie à métal actif ou à insertion de métal actif comprenant une structure protectrice conductrice d'ions comprenant une couche imperméable conductrice de métal actif (tel que du lithium) séparée de l'électrode (anode) par un séparateur poreux imprégné d'un électrolyte non aqueux (anolyte). Cette structure protectrice empêche le métal actif de réagir de façon délétère avec l'environnement sur l'autre côté (cathode) de la couche imperméable, qui peut comprendre des électrolytes liquides, aqueux ou non aqueux (catholytes) et/ou une variété de matériaux électrochimiquement actifs, tels que des oxydants liquides, solides et gazeux. Cette invention concerne également des additifs et des conceptions de sécurité qui facilitent la fabrication.

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