Proton-catalysed reactions in which water is not a...

Details Proton-catalysed reactions in which water is not a... Proton-catalysed reactions in which water is not a...

C - Chemistry, Metallurgy

07

C

260/212, 260/648

C07C 43/04 (2006.01) B01J 21/16 (2006.01) C07C 41/06 (2006.01) C07C 45/74 (2006.01) C07C 69/02 (2006.01) C07C 209/64 (2006.01) C07D 295/023 (2006.01) C07D 317/12 (2006.01) C07D 317/14 (2006.01) C07D 319/12 (2006.01)

Patent

CA 1154014

ABSTRACT OF THE DISCLOSURE The invention relates to the use of metal cation-exchangeable layered clays in organic reactions catalysed by protons in which water is not a stoichiometric reactant, Such organic reactions include the reaction of an olefin with a carboxylic acid in the liquid or vapour phase to produce an ester, e.g. reaction of ethylene with acetic acid to produce ethyl acetate, reaction of an alkanol with linear olefin at temperatures above 100°C to produce an ether, the conversion of primary or secondary aliphatic alcohols or polyols into ethers, the conversion of primary or secondary amines into secondary and tertiary a?ites respectively and the reaction of an olefin with benzene to produce an alkyl benzene.

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