Proton conductor, process for its production and...

H - Electricity – 01 – B

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Details

H01B 1/06 (2006.01) H01B 1/04 (2006.01) H01B 1/12 (2006.01) H01B 13/00 (2006.01) H01M 8/02 (2006.01) H01M 8/10 (2006.01)

Patent

CA 2463454

A novel proton conductor which is usable in dry atmosphere or in a relatively wide temperature range including room temperatures and is remarkably improved in proton conductivity; a process for the production thereof; and electrochemical devices. Specifically, a proton conductor made of a fullerene having a proton-liberating functional group bonded thereto through an at least three-membered ring structure; electrochemical devices made by using the same; and a process for the production of the above proton conductor which comprises preparing a fullerene derivative to which a functional group having an ester group is bonded through an at least three-membered ring structure, hydrolyzing this derivative with an alkali hydroxide, and subjecting the resulting hydrolyzate to ion exchange to form a proton-liberating group.

L'invention concerne un nouveau conducteur protonique utilisable dans une atmosphère sèche ou dans une fourchette thermique relativement large comprenant les températures ambiantes, ledit conducteur étant considérablement amélioré au niveau de la conductivité protonique. Cette invention a aussi trait à un procédé de fabrication correspondant et à des dispositifs électrochimiques. L'invention a, notamment, pour objet un conducteur protonique constitué d'un fullerène possédant un groupe fonctionnel à libération protonique lié par le biais d'une structure en anneau comprenant au moins trois éléments, des dispositifs électrochimiques contenant ce conducteur, et un procédé d'élaboration du conducteur protonique susmentionné consistant à préparer un dérivé de fullerène, auquel un groupe fonctionnel ayant un groupe d'ester est lié par le biais d'une structure en anneau comprenant au moins trois éléments, à hydrolyser ce dérivé avec un hydroxyde alcalin, et à soumettre l'hydrolysat résultant à un échange ionique, de manière à former un groupe de libération de protons.

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