Pyroelectrochemical process for reprocessing irradiated...

C - Chemistry – Metallurgy – 22 – B

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C22B 60/02 (2006.01)

Patent

CA 1126961

ABSTRACT OF THE DISCLOSURE: The invention is concerned with a pyroelectrothemical method for the reprocessing of irradiated nuclear fuels, characte- rized in that it comprises the steps of dissolving the nuclear fuel, containing fission products, in a bath comprising molten alkali metal sulfates; thermally decomposing the plutonium sul- fate Pu(SO4)2, formed in said molten bath to plutonium oxide, PuO2; electrodepositing uranium oxide, on the cathode of an elec- trolytic cell provided in said molten bath; recycling the melted sulfates of said molten bath to the start of the process; and conditioning said fission products and the said melted sulfates. The process according to the invention is more particularly usa- ble for a final disposal of said melted salts and fission products.

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