Radiation curable coating containing polyfluorooxetane

Details Radiation curable coating containing polyfluorooxetane Radiation curable coating containing polyfluorooxetane

C - Chemistry, Metallurgy

08

G

C08G 18/50 (2006.01) C08F 290/06 (2006.01) C08G 18/67 (2006.01) C08G 65/18 (2006.01) C08G 65/22 (2006.01) C09D 163/10 (2006.01) C09D 175/16 (2006.01) G03F 7/038 (2006.01)

Patent

CA 2369142

Acrylate, or methacrylate, or allylic, functionalized polyfluorooxetanes are disclosed for use in radiation curable coating compositions. These acrylate, or methacrylate, or allylic, functionalized polymers provide improvements in wetting and surface properties that have previously been provided by migratory chemicals such as waxes and oils. The partially or fully fluorinated side groups of the fluorooxetanes are believed to be disporportionately present at the interfaces between the coating and the substrate and between the coating and the atmosphere.

La présente invention concerne des polyfluorooxétanes fonctionnalisés avec des groupes acrylate, ou méthacrylate, ou allylique, destinés à des compositions de revêtements durcissables par rayonnement. Ces polymères fonctionnalisés à l'aide de groupes acrylate, ou méthacrylate, ou allylique, permettent d'obtenir des améliorations de propriétés de surface et de mouillage précédemment obtenues au moyen de spécialités chimiques migrantes telles que des cires et des huiles. Les groupes latéraux totalement ou partiellement fluorés des fluorooxétanes sont censés être présents, de manière disproportionnée, aux interfaces entre le revêtement et les substrats et entre le revêtement et l'atmosphère.

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