Radiation-polymerizable cellulose esters

C - Chemistry – Metallurgy – 08 – F

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Details

400/1303, 117/18

C08F 251/02 (2006.01) C08B 15/06 (2006.01)

Patent

CA 1318046

ABSTRACT OF THE DISCLOSURE The present invention relates to a grafted cellulose ester prepared by reacting a cellulose ester containing residual hydroxyl groups with an acrylic based compound and m-isopro- penyl-.alpha.,.alpha.'-dimethylbenzyl isocyanate. The grafted cellulose ester is a urethane-containing product having pendant (meth)acrylate and .alpha.-methylstyrene moieties. The grafted cellulose ester is readily self-polymerizable in the presence of a photoinitiator upon exposure to ultraviolet radiation. It does not require the presence of vinyl monomers to become crosslinked. The grafted cellulose ester is useful as a protective/decorative coating for wood, metal, plastics, and other substrates. LE0862F

587482

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