Rate matched copolymerization

C - Chemistry – Metallurgy – 08 – F

Patent

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Details

C08F 2/38 (2006.01) C08F 2/00 (2006.01)

Patent

CA 2472630

A method for controlling copolymer architecture by a two-part process. In the first step, a monomer analysis is obtained from a test polymerization having constant rate co- monomer addition. In the second step a copolymer is polymerized using a co- monomer feed rate that has been adjusted based on the monomer analysis to produce a copolymer with highly controlled polymer architecture. The method can predict feeds rates to produce any desired polymer architecture from a purely random polymer to a tapered polymer. The method works for terpolymers as well as copolymers.

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