Recovery of 3,4-epoxy-1-butene from 1,3-butadiene oxidation...

C - Chemistry – Metallurgy – 07 – D

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C07D 303/04 (2006.01) C07D 301/10 (2006.01) C07D 301/32 (2006.01)

Patent

CA 2173235

Disclosed are improved processes for the recovery of 3,4-epoxy-1-butene (EpB) from an epoxidation effluent comprising EpB, butadiene, oxygen and butane obtained by the selective epoxidation of butadiene with an oxygen-containing gas in the presence of a catalyst and an inert gas. EpB is separated from the effluent by means of an absorption process using liquid mixture of butadiene and butane as the absorbent material. The inclusion of butane in the epoxidation and recovery processes permits the use of lower pressures in the absorption of the EpB product.

L'invention concerne des procédés perfectionnés de récupération du 3,4-époxy-1-butène (EpB) à partir d'un effluent d'époxydation contenant du EpB, du butadiène, de l'oxygène et du butane résultant de l'époxydation sélective de butadiène avec un gaz contenant de l'oxygène en présence d'un catalyseur et d'un gaz inerte. L'EpB est séparé de l'effluent au moyen d'un procédé d'absorption, dans lequel un matériau absorbant constitué d'un mélange liquide de butadiène et de butane est utilisé. L'addition de butane dans les procédés d'époxydation et de récupération permet d'utiliser des pressions plus basses dans l'absorption du produit EpB.

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