Recovery of fluoride values from waste materials

C - Chemistry – Metallurgy – 01 – B

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C01B 9/08 (2006.01) C01B 7/19 (2006.01) C01F 7/50 (2006.01) C02F 1/00 (2006.01) C25C 3/08 (2006.01)

Patent

CA 1322649

- 1 - A B S T R A C T A process for the treatment of waste materials such as spent cathode liners involving combustion of the contained carbonaceous material, decomposition of the contained cyanides, sulphides and nitrides, and recovery of fluoride values by a sulpholysis reaction, is characterized in that the sulpholysis reaction is carried out in a separate stage. The process enables a recovery of fluoride values from smelter wastes which is especially favourable environmentally. A further advantage of the invention is that recovery of the contained fluoride values, initially in the form of gaseous fluoride species, may subsequently be treated with alumina to produce aluminium trifluoride, which is of significant economic importance.

555119

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