Recovery of nitric acid from nitration processes

C - Chemistry – Metallurgy – 07 – C

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C07C 205/06 (2006.01) C07C 201/16 (2006.01)

Patent

CA 2173381

A process for the removal and recovery of nitric acid, sulfuric acid and nitrous oxides (NO X) from the crude dinitrotoluene (DNT) obtained by nitrating with an acid, a benzene derivative selected from the group consisting of toluene or mononitrotoluene (MNT) after separation of said dinitrotoluene from said nitrating acid, wherein said crude dinitrotoluene is extracted in a plurality of steps whereby a dilute aqueous solution of nitric, sulfuric and nitrous acids countercurrently contacts said crude dinitrotoluene, said volume ratio of said dinitrotoluene to said aqueous solution being between 1:3 and 10:1, said extraction steps resulting in the formation of an aqueous extract which is blended directly into said nitrating acid for re-use in the acid nitration of said benzene derivative.

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