Recovery of zinc

C - Chemistry – Metallurgy – 25 – C

Patent

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204/74

C25C 1/16 (2006.01)

Patent

CA 1066658

ABSTRACT OF THE DISCLOSURE Iron-bearing zinc sulfide concentrates are leached with a sulfuric acid solution containing hexavalent chromium ions, e.g. chromic acid or a dichromate. The leach solution after separation from undissolved residue is hydrolyzed by heating under pressure at a temperature near or above the boiling point of the solution (ordinarily a range of from about 90°C to about 250°C ) to precipitate iron as a basic ferric salt. The iron precipitate is separated, the residual solution subjected to zinc dust purification, and the thus purified solution then subjected to a first bifluid electrolysis to electrowin zinc and to regenerate sulfuric acid and reoxidize trivalent chromium ions to hexavalent form. Anolyte discharged from the first electrolysis is subjected as anolyte in a second bifluid electrolysis to oxidize the remaining trivalent chromium to hexavalent form, and thereafter the solution is recycled to the leaching operation.

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