Redox flow battery

H - Electricity – 01 – M

Patent

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Details

H01M 10/44 (2006.01) H02J 3/38 (2006.01) H02J 7/00 (2006.01)

Patent

CA 2748146

A redox flow battery having a high electromotive force and capable of suppressing generation of a precipitation is provided. In a redox flow battery 100, a positive electrode electrolyte and a negative electrode electrolyte are supplied to a battery cell including a positive electrode 104, a negative electrode 105, and a membrane 101 interposed between the electrodes 104 and 105, to charge and discharge the battery. The positive electrode electrolyte contains a manganese ion, or both of a manganese ion and a titanium ion. The negative electrode electrolyte contains at least one type of metal ion selected from a titanium ion, a vanadium ion, a chromium ion, a zinc ion, and a tin ion. The redox flow battery 100 can suppress generation of a precipitation of MnO2, and can be charged and discharged well by containing a titanium ion in the positive electrode electrolyte, or by being operated such that the positive electrode electrolyte has an SOC of not more than 90%. In addition, the redox flow battery 100 can have a high electromotive force equal to or higher than that of a conventional vanadium-based redox flow battery.

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