C - Chemistry – Metallurgy – 08 – F
Patent
C - Chemistry, Metallurgy
08
F
C08F 210/16 (2006.01) C08F 4/68 (2006.01) C08F 10/00 (2006.01)
Patent
CA 2117954
REDUCED FOULING IN PROCESS FOR PRODUCTION OF EP Abstract of the Disclosure A process for producing EP and EPDM polymers with a reduction in fouling is provided, which process comprises polyemrizing ethylene, an alpha-olefin and a nonconjugated diolefin (if utilized) in a polymerization medium comprising a hydrocarbon diluent at a temperature of from about -50°C to about 150°C in the presence of a catalyst system comprising (a) a vanadium compound, (b) diethyl aluminum chloride, ethyl aluminum sesquichloride or ethyl aluminum dichloride and (c) an organo aluminum compound of the formula R3Al wherein R is an alkyl group having from 8 to 12 aarbon atoms and, optionally, triethyl aluminum, the molar ratio of chloride in each compound of (b) to the total aluminum content in (b) and (c) being specified and the ratio of the mols of vanadium compound to the total mols of said alkyl aluminum compound plus (c) being from about 1:10 to about 1:50 to the desired conversion.
Knauf Thomas Franz
Osman Akhtar
Padliya Dilipkumar
Bayer Inc.
Smart & Biggar
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