Reducible porous crystalline hybrid solid for the separation...

Details Reducible porous crystalline hybrid solid for the separation... Reducible porous crystalline hybrid solid for the separation...

C - Chemistry, Metallurgy

07

C

C07C 7/13 (2006.01) B01D 53/04 (2006.01)

Patent

CA 2726261

The present invention relates to reducible porous crystalline solids, constituted of a metal-organic framework (MOF), for the separation of mixtures of molecules having different degrees and/or a different number of unsaturations with a selectivity that can be adjusted by controlling the reduction of the MOF. The MOF solids of the present invention have, after reduction, a strong affinity for molecules containing at least one unsaturated group. They may be used in various separation processes, especially those concerning hydrocarbons.

La présente invention se rapporte à des solides cristallin poreux réductibles, constitués de réseau métal- organique ou Metal-Organic Framework (MOF), pour la séparation de mélanges de molécules ayant des degrés et/ou un nombre d' insaturations différents avec une sélectivité modulable par un contrôle de la réduction du MOF. Les solides MOF de la présente invention ont après réduction une forte affinité pour les molécules contenant au moins une insaturation. Ils peuvent être utilisés dans divers procédé de séparation, notamment ceux concernant les hydrocarbures.

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