Reducing copper corrosiveness of organic polysulfides

C - Chemistry – Metallurgy – 07 – C

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C07C 319/28 (2006.01) C07C 319/22 (2006.01) C07C 321/14 (2006.01)

Patent

CA 2062391

Reducing the copper corrosiveness of dihydrocarbyl polysulfides by treating them with an alkali metal-containing or alkaline earth metal-containing substance capable of dissolving elemental sulfur (e.g., sodium hydroxide or sodium sulfide). The process is conducted in a liquid reaction medium composed of a mixture of water and at least one water-soluble alcohol. Experiments have shown that it is possible by use of this process to reduce the copper corrosiveness to a level below that exhibited by a product formed by treating the same initial dihydrocarbyl polysulfide in the same way but in a liquid medium composed solely of water.

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